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Chemistry  /  Chem 2335  ·  Atom · ~20 seconds

Classifying Oxygen Compounds by O-O Bonding

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Oxygen compounds sort into oxides (isolated O2−), peroxides (an O-O single bond, bond order 1), and superoxides (a stronger O-O bond of order 1.5, carrying 1− charge per two oxygens).

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Sodium peroxide, Na2O2, has a covalent O-O bond that ordinary sodium oxide, Na2O, lacks.

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All three classes look alike as "metal plus oxygen"; oxygen count in the formula, not appearance, distinguishes them.

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